Chemistry Blog

«

»

Sep 06

Lab Horror Stories

by mitch | Categories: chemical safety | (41750 Views)

After Jyllian Kemsley’s story on the non-supervised cavalier graduate student and his missing fingers, members of the chemistry reddit shared their own harrowing experiences around the lab. I would suggest we all try to learn something from these stories, the most important lesson being always wear your safety glasses!

bri1232001:

I work in a chemistry lab and last week an intern was involved in an accident. The intern sealed a glass vial with water and dry ice inside. The vial exploded and glass shrapnel gave him multiple lacerations on his face and arms. He was taken to the emergency room where he received stitches. His safety glasses had some extensive chips removed from them. He was very lucky to have had them on.

myarlak:

I saw someone get 2 large drops of sulfuric acid on their arm, and the acid ran down their arm about 4 in. they now sport scars that look like something with large fangs bit their arm and ripped… I personally have been sprayed in the face with phenyl Grignard, not horrible but burns when it gets on you, burns when you wash it off. I saw a gas tight syringe full of diethyl zinc lose it’s gas tightness, caused a small fire and that was it. I saw the results of someone leaving lithium open in a glove box… melted through one layer of steel and bowed the 2nd layer as it burned in nitrogen… that’s about it, mostly a bunch of close calls.

simplemathtome:

two postdocs were working in the glovebox next to me. They spilled some MeLi and were mopping it up with kimwipes. They knew it would be dangerous when they pulled it out of the antechamber, so they prepared an EtOH bath (which, to be fair would safely neutralize a small amount of MeLi, iPrOH would have been better). One postdoc opens the antechamber and, as quickly as possible, took the kimwipes out and dunked them in the EtOH bath, only problem was, the kimwipes burst into flames as soon as the kimwipes were exposed to air, setting the bath on fire. In the panic, one of the postdocs went to get MORE ETOH and poured it on the fire. The bath overflowed, she started yelling for liquid nitrogen, I got out of my box and started running towards the liquid nitrogen. The next thing I know, i hear screaming, the postdoc walks out of the lab (right under a safety shower, without pulling the water release) with her entire pantleg on fire. I cant find LN2 so I take off her labcoat and snuff out the fire on her leg. The other postdoc managed to put out the EtOH fire, but he didnt remember how he did it. They both went to the hospital, one of them stayed for 2 weeks. That was my first summer in a lab, right before sophomore year.

sprouts42:

Teaching a group of 13 year olds a few months ago showing them the decomposition of limestone and running the gas through limewater to show carbon dioxide. You have to get the limestone really hot in a boiling tube using the bunsen. After the practical was over I told the students to turn off the bunsen forgetting to tell them to remove the delivery tube from the limewater. Almost simultaneously the sound of limewater rushing up the delivery tube into the boiling tube and causing it to explode 15 times over. Screaming girls all over the place and glass showering everywhere. Another safety glasses save the day moment.

shyguysays:

When I was in organic lab, my TA closed my heating reaction flask a little too tightly. It blew up. I pulled three pieces of glass out of my forehead right above my right eyebrow. The stopper hit my partner in the head. We lived long enough for the department to let us graduate.
Yay for goggles!

theddman:

My lab neighbor (synthetic organic, read: the jocks of chemists) was running a huge silica column that burst all over him because his girlfriend was distracting him. He had to use the emergency shower!

Same lab neighbor blew up another column or something with concentrated TFA in it, he has a few cigarette-looking burns on his arms from it.

I personally was making some 10 M NaOH in a conical 50 mL tube (“Falcon” tube) early in my career. I added the pellets and the water, closed the screw cap tight and shook vigorously to dissolve it. Well, of course dissolving NaOH in water is highly exothermic. Yep, the entire thing blew the eff up and got NaOH all over me, my bench, and even the ceiling. Luckily I didn’t get burned anywhere important because I was wearing safety glasses.

I overfilled an ultra filtration device with very VERY expensive compound, lost half into the centrifuge rotor. Effing pipetted that shit out and HPLC purified it (shhh, don’t tell the boss!).

I could go on and on…labs are filled with dangerous things and overly curious hands.

thelt:

Last year in our lab we had a 4L waste jug of Piranha (3:1 conc. H2SO4:conc H2O2) solution explode, actually more like geyser, all over the lab. Thankfully no one happened to be in the lab otherwise they would have been fucked. Pretty much everything within about a 10 ft radius of where the jug was destroyed. The paint peeled off the walls and ceiling, lights had to be replaced everything. Hazmat team had to be called in to clean up the mess. For about the next week or so I couldn’t stand to be in the lab for more than about 20 minutes or so before my throat would start to burn.

Note: When storing waste piranha don’t cap the bottle.

smilingfreak:

Well, I’m a comp. chem, so there was that one time I spilled coffee on my lap. It was like, really, really hot.
Yeah.

Screw you all! I’m a real chemist! Honest!

erallured:

I worked in the stockroom in undergrad and was unsupervised a lot, especially in the summer. I was messing around and made some NI3. I knew it was really unstable when dry, so I took just a spatula tip of it out of the beaker and spread it on some filter paper. It couldn’t have been more than a milligram or two. I was working in a fume hood in an empty lab away from anyone else. I kept pressing on the thin streak of powder trying to set it off but it wasn’t going. I decided maybe I didn’t have enough/it was too spread out, so I was going to add some more. I used the spatula to move the paper slightly, and apparently it had dried and this small movement was enough to set it off.

¡BOOM!

I was instantly deafened and after a couple seconds had a loud ringing in my ears. A few seconds after that, a research student opened the doors and walked it. She said something to me, but I couldn’t hear so I just said “hi” and smiled, hoping she was just greeting me. She walked away with no indication she knew anything was up and gradually my hearing came back. I have no idea how she didn’t hear anything, she must have only been a few feet from the lab door when it happened. I was so shaken up, I dumped the rest (I had a good 5-6g of precipitate) into a waste jar and got out of there. All in all, not the worst, but for a few minutes, I thought I’d lost my hearing permanently.

DessicatedDogsDick:

A guy in my lab was cutting titanium sponge off an electrode (molten salt process) when it caught fire. There was probably around 2 kilos of the shit that went up in a very large, hot fire. He emptied two CO2 extinguishers onto it, which only made it worse. In desperation, he picks up the metal tray it’s sitting on (still burning) and bolts outside. The tray melted through just as he reached the door. The lab bench and stuff around were basically ruined from the heat.

zlukasze:

I was adding “dry” ether to stannic chloride, prepping to make tetrachlorobis(DMSO)tin(IV).S omeone had mislabeled the ether, and it apparently had a very high water content because the lab promptly filled with hydrogen chloride gas and shrapnel. The space abutted some department offices and they had to be evacuated.

Farrar:

There was a pretty bad one where someone had to go to hospital; they were pressing the bung onto a conical flask, when the glass smashed. Because of how they were holding it, a rather large piece sliced up their arm, slashing open their wrist and it required quite a few stitches.

There was also an incident where an evaportating dish exploded and it cut open atleast three students, but luckily those were only minor surface injuries.

Oh, and one where someone ate some copper sulphate and had to have their stomach pumped…but that’s more of a ‘don’t be so stupid’ rather than a horror story…

calladus:

In high school chemistry class, way back in ’81 or ’80. Due to budget problems, the chemistry teacher was let go and the job was given to the woman who usually taught English. Class was pretty boring – very few experiments, mostly reading and explanations of what “ought” to happen when this is mixed with that.

But there was one experiment with mercury that she wanted us to do. So she went into the chemical storage area, and came out with a container of mercury. It was a very heavy container – well over 20 pounds. She dropped it.

Mercury ran in little balls all around the classroom. To fix it, the teacher gave us all 5×9 index cards and had us scoop the mercury together to the middle of the classroom where she swept it all up with a broom and dustpan and returned it to the container.

When everything was “cleaned up”, we all continued with class. The container of mercury was put back into the chemical storage area. As far as I know, she never mentioned this to the principle, or anyone else..

barrysagittarius:

I worked two years in an Organic Lab and two years in a Chemical Physics laser lab. The worst two to strike me were: – In my organic lab I was putting glassware in some basebath and the flask dropped from my tongs. As it sunk, the air escaping splashed bath into my face. Some minor scars on my forehead and thank god for my safety glasses :D – In my laser lab, i passed through the beam path; a common practice since the laser is focused – usually – inside the reaction chamber. However this time, one of the beams was focused outside and I brought my hand through it. I still remember the SNAP sound and the burning feeling inside my hand. Much fun.

The worst things happened to others in my lab. I spent a summer making precursors for this very lengthy organometallic compound we were making. One of the reactions was to bromenate a compound and was HIGHLY reactive – I was adding the bromine solution dropwise while the target flask was at -5C and it still fizzled with each drop. Anywho, after the reaction, it had to be quenched and washed with ether. After I did this on a 100mL scale a couple times, the grad student I was working with decided to try and scale it up to 1L (…). I was out the day, but when I came in the hood was brown. And the floor, and the ceiling, and… and we had much less glass ware, including the entire glass vacuum line. Apparently he didn’t completely quench it, and with one shake in the separation flask (can’t remember the name, been a while) it exploded. Horrible chemical burns and stiches later… he was back at it a week later.

The second worst thing was my laser lab. Me and a grad student were building an electron gun from spare parts for an experiment. We had to hack together the power feed into the vacuum chamber, so it was just a flange with a bunch of copper leads. To power the gun, we used these flimsy connectors we had to clip on and off the leads (until we got the final connectors in). Oh and our Power Supply was 10kV floating (in a lucite box :D). Well, again, I was out sick, and my grad student got his thumb too close to one of the leads and WHAMMO! 10kV to the chest; blown across the room into a wall but otherwise okay.

relampaguear:

At first here, I must confess this happened to my lab partner and not myself. I work in an organic lab that does a lot of solid phase peptoid synthesis, and after the desired residue length is reached, we cleave the peptide from the resin using TFA. My lab partner was using a 10 mL syringe to measure the aliquot needed and pulled the stopped out all the way, splashing concentrated TFA all over her face and arms. Thankfully the only lasting casualties were her goggles and a gnarly scar above her eyebrow.
Go goggles go!

abyssuk:

I used to work for a major peptide synthesiser in the UK. The worst part of a peptide SSPS (solid state peptide synthesis) reaction is the cleaving of the peptide at the end from a silica bead basically. Most times this can be done with TFA but for some more difficult peptides you need to cleave with 99% HF gas cooled to a liquid with solid CO2 pellets in polypropylene flasks. All contained in specialist equipment from pressurised cylinder to flask in a fume hood. . I’ll stress now It wasn’t me who did this.. but once the poor soul who was doing the reaction couldn’t open the HF cylinders valve because it was rusty.. so hit it with a hammer!! The valve broke off and the HF gas started venting out to air very quickly. The whole building was evacuated very quickly and the fire brigade was called out, luckily nobody was hurt as the hood vented most of the gas out of the building. Afterwards once the fire brigade deemed it safe the damage to the fume hood and roof of the building looked like that scene in aliens.

pfschmit:

I was making a catylist using LiAlH4 and reacting it with a diglycol, not realizing a byproduct was H2O. I soon found out when the temperature went through the roof and a explosion followed. Fortunately, I had a blast shield in fromt of the flask. Nice fire though

palad:

In high school, our chem instructor warned us very clearly about the flammability of acetone. So naturally, my lab partner and I wanted to see if our teacher was correct. On the last day of a week-long lab, after everything had been cleaned up, we filled a small beaker with acetone and carefully placed it in one of the deep sinks. As I lowered the lit match toward the mouth of the beaker, I failed to notice the puddles of acetone spilled on the tabletop moments before by other students. One giant WHOOOSH later, and we had the attention of every student in the room, including those 30 feet away who claimed they felt a wall of heat blow past them. Fortunately, the acetone was the only thing flammable nearby, and it quickly burned itself out.

When I got home that afternoon and looked in the mirror, I started wondering why some of my hair had changed color. As I touched it and it flaked away into ashes, I realized just how close the flames had come.

merlin2112:

Around 12 years ago, I was given the task of preparing Azomethane. No, not Diazomethane, but Azomethane. This was to be used on the surface of Pyrite via FABMS. Anyway, the procedure called for: dimethyl hydrazine NaOH H2O Mercuric Oxide Following a reference (see Surface Science(279)79(1992)) the procedure is fairly straightforward; the problem lies when You have to evaluate the solid Azomethane to determine if any color is present.

After making ~25gm of Azomethane a normal procedure was called when I had to wipe off the frozen vacuum tube. POP! The tube exploded, giving Me lascerations to my hand, side of my face, and shattered my glasses, which gave Me a lascerated cornea!

Luckily all glass was removed and I was back in the lab after 7 days recovery making Azomethane again!

Mitch




11 comments

Skip to comment form

  1. Noel

    Heard this one from Pat Shapley during TA meeting:

    Back in the days they used to clean benchtops and columns with benzene. In those same days, they also allowed smoking in lab. One day, a postdoc lit up in lab with next to a open column of benzene. It sparked an explosion followed by fire. It took a while, but the students managed to put out the fire. Pat said that she was coughing up black tar for days after that.

  2. Loïc

    Well, you know, in my high school, we once made 250 ml of fluorhydric acid solution.
    We were 17, unprotected (some of us had safety glasses, but not all) and thought it was pretty cool to see the glass being not wettened bye the “water”.

  3. excimer

    Well, I’m a comp. chem, so there was that one time I spilled coffee on my lap. It was like, really, really hot.
    Yeah.

    Screw you all! I’m a real chemist! Honest!

    Win

  4. Fleaker

    I would have pressed criminal charges against erallured if he had done that in my laboratory. Putting NI3 in the waste and leaving it be for others to be not so pleasantly surprised, that’s downright negligent and criminally so. Making things like that in that quantity, enough for it to detonate just by the weight of its own crystal mass shows how irresponsible some chemists are. He/She’s lucky they didn’t lose more than temporary hearing. Good thing he wasn’t my coworker, or I’d have personally put him in the hospital.

    I had an NSF REU intern add all of the bromobenzene all at once at the 500 mL scale. Sure enough it didn’t start at once, it waited until he added a crystal of iodine. Old Faithful surely erupted creating a heck of a mess.

    I’ve had a few things go wrong, some of them more serious than what’s been shared so far. I can tell you all this: liquid Li at 500K is much worse than liquid Cs, at least in what it does to glass/quartz/ceramic. Having now synthed all the alkali elements, I can say lithium is the worst to deal with!

    I had a small fire when making ketene to make my own acetic anhydride via pyrolysis of acetone.

    I had neat 500*C SO3 with SO2 destroy FEP tubing (literally ashed it). Also turns silicone tubing back into SiO2 :-) I have pictures on that one.

    I did have a minor yet painful HF burn that happened through two gloves. I hate working with HF. Past the 48% stuff, it gets very, very fluid and fumes quite a bit.

    Closest I came to a bad injury was when I was cleaning out a flask with AlBr3 in it. Got a shot of HBr to the face (thank you safety goggles!!!).

    Had a nitration go very wrong.

    Never had any of the usual stuff like LAH fires, unintentional alkali metal fires, sulfuric acid burns.

    The rest of it, I plead the 5th :P

  5. grubber

    only got an almost-accident.

    we were working on our stills, trying to get the system neater. apparently, one of the other PhD’s rewired the ether still incorrectly. I was in charge of that one, so when I saw it refluxed but didn’t collect anything, I slightly raised the temp. it was pretty full, so no problems there. when still nothing happened after an hour, I tried checking the setup for leaks. when I touched one of the stoppers, I had a beautiful blue geiser. I got away just in time. blew the door off its hinges, leaving me with only a frizzled eyebrow.

    pics on request ;)

  6. Chemjobber

    Consider the request made.

  7. mitch

    We definitely need to see pics. :)

  8. azmanam

    Sounds like the plot of an SNL MacGruber skit… coincidence with op’s name???

  9. southey

    Yesterday I spilled quite a lot LiAlH4 in my Braun glove-box. The box looks ok with O2 level around 3.5 ppm, H2O level below 0.1 ppm at that time. After a while I tried to tide up with tissue which has been in the box for more than one month.
    In the beginning it was ok. But when I tried to brush the balance with tissue, a small fire happened!!!
    That’s quite terrible. Does that means the O2 level in the box is not right? Most stangely the O2 level came up to around 39 ppm after the fire immediately. I checked carefully there is no leakage at all. Now it gradually dropped to around 13 ppm after one night.
    Can anyone give me some eexplanation? Thanks a lot

  10. Thomas Williams

    Several years back the company representative that refills the concentrated acid and base in our acid tank did so without his safety goggles. He had probably filled tanks thousands of times with no issues. Unfortunately, he dumped concentrated base into the partially filled acid reservour. Exothermically, it rushed from the container and hit him right in the face. Initially, he though he was ok…. walked down the hall looking for the boys-room. Passed one room and by the time he got to the 2nd realized he was in trouble. He got lucky…. it was art class (with a fully equiped dark room (and as such emergency eye wash).

    A custodian saw the man and related to me that one eye seemed to be twice the size of normal. Don’t know how much exageration was involved. I heard that he has eye issues but didn’t lose his sight.

  11. Julien

    Once during a practical course, had to make phenyl grignard in ether. Magnesium was kinda unreactive, and only after adding all the bromobenzene, dibromoethane and iodine the reaction seemed to be slowly starting. When i came back the next morning the hood was filled with magnesium flakes and the rest was a dark stain on the ceiling. The glassware was completely intact!
    During my phd a colleague dropped 50 g lialh4 first scooped up the glass, the then decided to rinse the dustpan that had some hydride left on it. It sparked, one of the sparks falling onto the 50 g of lialh4 on the floor. Thats when she screamed “fire!” I ran there with someone else who was carrying a fire extinguisher, a water one… using it on the fire created an acrid smoke and pushed the fire back towards the organic waste vessels, but fortunately got extinguished before.

Leave a Reply

Your email address will not be published. Required fields are marked *

You may use these HTML tags and attributes: <a href="" title=""> <abbr title=""> <acronym title=""> <b> <blockquote cite=""> <cite> <code> <del datetime=""> <em> <i> <q cite=""> <strike> <strong>