Chemistry Blog

Tag Archive: Azides

Aug 28

Explosive Solutions


Instead of starting at the beginning of a paper I want to kick off this commentary with a statement from near the end: “Caution! Covalent azides are potentially hazardous and can decompose explosively under various conditions! Especially Hg2(N3)2, α– and β-Hg(N3)2, and [Hg2N]N3 in this work are extremely friction/shock-sensitive and can explode violently upon the …

Continue reading »

Sep 26

Life in Chemical Development, Part 2.


In the first part of this little series I recounted my experience with two steps of a four-step sequence, now I would like to move on to the last two steps: The preparation of a benzyl chloride and it’s conversion to a benzyl azide. If you remember I had to convert 7098 kg of the …

Continue reading »