Chemistry Lab Demonstrations: Upsidedown Thunderstorm
Posted by : azmanam | On : 17-02-2009 | Comments 13
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SN2 lab today. Preparation of (2-methylphenoxy)acetic acid from o-cresol and sodium chloroacetate. NaOH deprotonates cresol. Add sodium chloroacetate and reflux. SN2 reaction occurs. Acidify, collect the precipitate, and recrystallize from water. Unfortunately, today’s lab took a really long time. I’m not sure why, but it did.
Anyway, I looked around for cool SN2 demos… and there really aren’t any. Sure, I can do the Finkelstein at different concentrations and show that one precipitates NaCl faster than another because it is more concentrated. Woo hoo. That’s not very exciting. So I ultimately decided that today’s lab just isn’t going to have anything to do with the SN2 reaction.
I decided to do the upsidedown thunderstorm. That’s my name. I’ve seen ‘thunderstorm in a test tube,’ but that’s not a very flashy name, now is it?
Here’s the deal: Add a layer of con’c sulfuric acid to a test tube (use all proper precautions for handling con’c acid!). Slowly and carefully add ethanol down the side to create an ethanol/acid biphase (if you leave it sit too long, the acid and ethanol will mix, so don’t let that happen). Add a few crystals of finely-ground potassium permanganate. The reaction occurs, and evolves a gas. The gas bubbles through the ethanol layer and looks...













