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Chemistry Lab Demonstrations: Upsidedown Thunderstorm

Posted by : | On : 17-02-2009 | Comments 13
*For more cool stories, pictures, and videos of chemistry demonstrations, click here* SN2 lab today.  Preparation of (2-methylphenoxy)acetic acid from o-cresol and sodium chloroacetate.  NaOH deprotonates cresol.  Add sodium chloroacetate and reflux.  SN2 reaction occurs.  Acidify, collect the precipitate, and recrystallize from water.  Unfortunately, today’s lab took a really long time.  I’m not sure why, but it did. Anyway, I looked around for cool SN2 demos… and there really aren’t any.  Sure, I can do the Finkelstein at different concentrations and show that one precipitates NaCl faster than another because it is more concentrated.  Woo hoo.   That’s not very exciting.  So I ultimately decided that today’s lab just isn’t going to have anything to do with the SN2 reaction. I decided to do the upsidedown thunderstorm.  That’s my name.  I’ve seen ‘thunderstorm in a test tube,’ but that’s not a very flashy name, now is it? Here’s the deal:  Add a layer of con’c sulfuric acid to a test tube (use all proper precautions for handling con’c acid!).  Slowly and carefully add ethanol down the side to create an ethanol/acid biphase (if you leave it sit too long, the acid and ethanol will mix, so don’t let that happen).  Add a few crystals of finely-ground potassium permanganate.  The reaction occurs, and evolves a gas.  The gas bubbles through the ethanol layer and looks...