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	<title>Chemistry Blog &#187; safety chat</title>
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		<title>Safety Chat: Nitric Acid Waste</title>
		<link>http://www.chemistry-blog.com/2009/06/14/safety-chat-nitric-acid-waste/</link>
		<comments>http://www.chemistry-blog.com/2009/06/14/safety-chat-nitric-acid-waste/#comments</comments>
		<pubDate>Sun, 14 Jun 2009 21:04:34 +0000</pubDate>
		<dc:creator>mitch</dc:creator>
				<category><![CDATA[general chemistry]]></category>
		<category><![CDATA[isopropanol]]></category>
		<category><![CDATA[nitric acid]]></category>
		<category><![CDATA[safety]]></category>
		<category><![CDATA[safety chat]]></category>

		<guid isPermaLink="false">http://www.chemistry-blog.com/?p=1926</guid>
		<description><![CDATA[
We&#8217;re going to be taking time out of our regular blogging schedule to remind everyone about better lab safety practices. Recently at Lawrence Berkeley National Laboratory someone poured isopropanol into an acid waste container of aqua regia. Aqua regia contains nitric acid, and the reaction for those unfamiliar with nitric acid&#8217;s oxidizing power is thus,

Due [...]]]></description>
			<content:encoded><![CDATA[<div style="float:right; padding: 0px 0px 10px 10px;"><a href="http://www.chemistry-blog.com/wp-content/uploads/2009/06/aqua-regia.jpg"><img src="http://www.chemistry-blog.com/wp-content/uploads/2009/06/aqua-regia-150x112.jpg" alt="aqua regia" title="aqua regia" width="150" height="112" class="alignnone size-thumbnail wp-image-1943" /></a></div>
<p>We&#8217;re going to be taking time out of our regular blogging schedule to remind everyone about better lab safety practices. Recently at Lawrence Berkeley National Laboratory someone poured isopropanol into an acid waste container of aqua regia. Aqua regia contains nitric acid, and the reaction for those unfamiliar with nitric acid&#8217;s oxidizing power is thus,</p>
<p><img src="http://www.chemistry-blog.com/wp-content/cache/tex_48eb0bbace13d33c8ef75e377e4634ab.png" align="absmiddle" class="tex" alt=" \text{C}_3\text{H}_7\text{OH} + \text{HNO}_3 \rightarrow \text{CO}_2 + \text{NO}_2 + \text{H}_2\text{O} \text{ (Good Luck Balancing This One)}" /></p>
<p>Due to the pressure in the waste container, the bottle blew and spewed its golden goodness throughout the room. It fractured the safety sash, and could have really hurt someone.</p>
<p>The lessons you should take home:</p>
<ul>
<li> Get rid of strong oxidizing acid waste as you generate it.</li>
<li>Do not trust others near your waste bottles. Don&#8217;t let others add to them.</li>
<li>If you generate strong acid wastes, probably a good idea that everyone from the undergrads and lab techs to the postdocs are made aware of the incompatibility of organics and nitric acid. <strong>You can&#8217;t expect chemists to have this knowledge anymore.</strong> <img src='http://www.chemistry-blog.com/wp-includes/images/smilies/icon_sad.gif' alt=':(' class='wp-smiley' />  </li>
</ul>
<p>Mitch</p>
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